What is a first-order reaction? Determine the integrated rate equation for a first-order reaction $R \to P$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) First-order reaction: $A$ reaction in which the rate of reaction is proportional to the first power of the concentration of the reactant $R$ is called a first-order reaction.
The rate of a first-order reaction $\propto [R]^1$.
For the reaction $R \to P$,the differential rate expression is:
$Rate = -\frac{d[R]}{dt} = k[R]$
$\therefore \frac{d[R]}{[R]} = -k dt \dots (i)$
Integrating this equation on both sides:
$\int \frac{d[R]}{[R]} = -\int k dt$
$\ln [R] = -kt + I \dots (ii)$
Here,$I$ is the constant of integration.
When $t = 0$,$[R] = [R]_0$,where $[R]_0$ is the initial concentration of the reactant. Substituting these values into equation $(ii)$:
$\ln [R]_0 = -k(0) + I \implies I = \ln [R]_0 \dots (iii)$
Substituting $I = \ln [R]_0$ into equation $(ii)$:
$\ln [R] = -kt + \ln [R]_0 \dots (iv)$
Rearranging the terms:
$kt = \ln [R]_0 - \ln [R]$
$kt = \ln \frac{[R]_0}{[R]}$
$k = \frac{1}{t} \ln \frac{[R]_0}{[R]} \dots (v)$
Converting to base $10$ logarithm:
$k = \frac{2.303}{t} \log \frac{[R]_0}{[R]} \dots (vi)$
Taking the antilog of equation $(iv)$,we get:
$[R] = [R]_0 e^{-kt} \dots (vii)$

Explore More

Similar Questions

$A$ and $B$ decompose via first order kinetics with half-lives $54.0 \, min$ and $18.0 \, min$ respectively. Starting from an equimolar non-reactive mixture of $A$ and $B$,the time taken for the concentration of $A$ to become $16$ times that of $B$ is ...... $min.$ (Round off to the Nearest Integer).

For the decomposition of azomethane,$CH_3N_2CH_{3(g)} \rightarrow CH_3CH_{3(g)} + N_{2(g)}$,a first order reaction,the variation in partial pressure with time at $600 \ K$ is given as shown in the graph. The value of the rate constant $k$ in $s^{-1}$ is $x \times 10^4$. Find the value of $x$.

The reaction $N_{2}O_{5} \longrightarrow 2NO_{2} + \frac{1}{2}O_{2}$ is first order in $N_{2}O_{5}$ having rate constant $6.2 \times 10^{-4} \ s^{-1}$. What is the value of rate of reaction when concentration of $N_{2}O_{5}$ is $1.25 \ mol \ L^{-1}$?

Point out the wrong statement for a first order reaction:

The rate constant of the decomposition of hydrogen peroxide is $0.0204 \text{ min}^{-1}$. Calculate the half-life of the reaction. (in $\text{ min}$)

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo